Document Type

Article

Publication Date

6-4-1993

Publication Title

Tetrahedron Letters

Volume

49

Issue

23

Publisher Name

Elsevier

Abstract

An intramolecular reductive Pauson-Khand reaction of the hexacarbonyldicobalt complex of N-(tert-butyloxycarbonyl)allylpropargylamine under dry-state adsorption conditions directly afforded the saturated N-BOC-3-azabicyclo[3.3.0]octan-7-one when the reaction was performed under an inert atmosphere. This bicyclic ketone was converted in several steps to the novel octahydro-1-azeto[2′,3′:3,4]cyclopenta[1,2-C]pyrrole ring system as confirmed by single crystal X-ray analysis.

Comments

Author Posting © Elsevier, 1993. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Tetrahedron, Volume 49, Issue 23, June 4, 1993. http://dx.doi.org/10.1016/S0040-4020(01)81870-6

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